[Treatise on Light by Christiaan Huygens]@TWC D-Link book
Treatise on Light

CHAPTER III
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And it will be found by the same reasoning, in this other figure, that when the piece C of the wave AC shall have reached the surface AB at B, all the portions of the wave AC will have advanced as far as BN, so that BC the perpendicular on AC is to AN the perpendicular on BN as 2 to 3.

And there will finally be this same ratio of 2 to 3 between the Sine of the angle BAD and the Sine of the angle FAN.
Hence one sees the reciprocal relation of the refractions of the ray on entering and on leaving one and the same transparent body: namely that if NA falling on the external surface AB is refracted into the direction AD, so the ray AD will be refracted on leaving the transparent body into the direction AN.
[Illustration] One sees also the reason for a noteworthy accident which happens in this refraction: which is this, that after a certain obliquity of the incident ray DA, it begins to be quite unable to penetrate into the other transparent substance.

For if the angle DAQ or CBA is such that in the triangle ACB, CB is equal to 2/3 of AB, or is greater, then AN cannot form one side of the triangle ANB, since it becomes equal to or greater than AB: so that the portion of wave BN cannot be found anywhere, neither consequently can AN, which ought to be perpendicular to it.

And thus the incident ray DA does not then pierce the surface AB.
When the ratio of the velocities of the waves is as two to three, as in our example, which is that which obtains for glass and air, the angle DAQ must be more than 48 degrees 11 minutes in order that the ray DA may be able to pass by refraction.

And when the ratio of the velocities is as 3 to 4, as it is very nearly in water and air, this angle DAQ must exceed 41 degrees 24 minutes.


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