[American Handbook of the Daguerrotype by Samuel D. Humphrey]@TWC D-Link bookAmerican Handbook of the Daguerrotype CHAPTER I 14/36
Experience has convinced me that a plate heated to about 80 deg.
before being exposed to iodine will present a far better defined image than a plate at a temperature of 50 deg.
I account for this by noticing that, at a higher temperature, the plate throws off any larger crystals that might otherwise be deposited, receiving only the finer, thus producing a more perfect chemical combination of iodide of silver. I would call the attention of the operator to this point, as presenting something of interest, and which may direct in a way of accelerating the future operations. That the presence of a film of moisture over the plate is a preventive of uniform chemical action, may be readily understood from the fact that iodine is almost insoluble in water, requiring seven thousand parts of water to dissolve one of iodine, or one grain to a gallon of water.
Yet its affinities for silver and other substances are so powerful as to prevent its existing in an insulated state, hence we can account for the frequent occurrence of a plate presenting parts of an image over its surface.
It is quite evident that those parts of plate's surface covered with moisture are nothing like as sensitive to the iodine as those parts perfectly free. Exposure of the plate in the Camera, and Position .-- The time of exposure necessary to produce an image upon the Daguerreotype plate, can only be determined by experiment, and requires a liberality of judgment to be exercised on the part of the operator.
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