[American Handbook of the Daguerrotype by Samuel D. Humphrey]@TWC D-Link bookAmerican Handbook of the Daguerrotype CHAPTER V 30/40
By adding the chlorides of strontian, uranium, potassium, sodium, iron, or copper to the liquid, various effects may be produced, and these bodies will be found to produce the same color on the plate that their flame gives to alcohol. "The honor of this discovery is due to M.Neipce.
Copper gives a variegated flame; hence many colors may be impressed on a plate prepared with a solution of its chloride. "M.
Neipce recommends a solution of the mixed chlorides of copper and iron, and it is with these, that I have been most successful.
As the chlorides of copper and iron are not much used in the arts, they are not generally found for sale in the shops; and it may be well to furnish those not much versed in chemistry with an easy method of preparing them. "They may be made directly from either metal by dissolving it in hydrochloric acid; but they may be formed by a cheaper method, and by which also the acid fumes are avoided. "Sulphate of iron or copper, or both together, may be dissolved in water and then neutralized with common crude potash, or its carbonate or bicarbonate--known commonly as pearl ash and saleratus.
If either of the latter be used, there will be formed sulphate of potash and a carbonate of the metal used, and there will also be a considerable effervescence of carbonic acid, which will, if care is not taken, cause the mixture to run over the vessel.
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