[American Handbook of the Daguerrotype by Samuel D. Humphrey]@TWC D-Link bookAmerican Handbook of the Daguerrotype CHAPTER V 3/40
The first process is to expose the plate to the heat of a spirit flame, until the silvered surface becomes of a well-defined golden-yellow color; then, when the plate is cold, take a piece of cotton, dipped in very dilute nitric acid, and rub lightly over it until the white hue is restored, and dry it with very soft clean cloths.
A weak solution of the hydriodate of potash, in which a small portion of iodine is dissolved, is now passed over the plate with a wide camel's hair brush.
The silver is thus converted, over its surface, into an ioduret of silver; and in this state it is exposed to light, which blackens it.
When dry, it is to be again polished, either with dilute acid or a solution of carbonate of soda, and afterwards with dry cotton, and the smallest possible portion of prepared chalk: by this means a surface of the highest polish is produced.
The rationale of this process is, in the first place, the heat applied dries off any adhering acid, and effects more perfect union between the copper and silver, so as to enable it to bear the subsequent processes.
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